- Chemical Name: ALPHA-FLUOROCINNAMIC ACID
- CAS No.: 350-90-3
Factory Sells Best Quality ALPHA-FLUOROCINNAMIC ACID 350-90-3 with GMP standards
- Molecular Formula: C9H7FO2
- Molecular Weight: 166.152
- Appearance/Colour: Solid
- Vapor Pressure: 0.00103mmHg at 25°C
- Melting Point: 156-159 °C(lit.)
- Refractive Index: 1.585
- Boiling Point: 289.3 °C at 760 mmHg
- PKA: 2.25±0.10(Predicted)
- Flash Point: 128.7 °C
- PSA： 37.30000
- Density: 1.275 g/cm3
- LogP: 2.08160
ALPHA-FLUOROCINNAMIC ACID(Cas 350-90-3) Usage
|
General Description |
α-Fluorocinnamic acid undergoes decarboxylation reaction on heating in the presence of copper to yield β-fluorostyrene. |
InChI:InChI=1/C9H7FO2/c10-8(9(11)12)6-7-4-2-1-3-5-7/h1-6H,(H,11,12)/b8-6-
350-90-3 Relevant articles
Low-temperature 19F NMR spectroscopy of 1-fluoro-1-lithioethenes - Stability, shifts and unexpected coupling constants
Kvicala, Jaroslav,Hrabal, Richard,Czernek, Jiri,Bartosova, Ivana,Paleta, Oldrich,Pelter, Andrew
, p. 211 - 218 (2007/10/03)
Half-lives and fluorine atom shifts of s...
Toward (Z)-selective Horner-Wadsworth-Emmons reaction of aldehydes with 2-fluoro-2-diethylphosphonoacetic acid
Sano, Shigeki,Teranishi, Rie,Nagao, Yoshimitsu
, p. 9183 - 9186 (2007/10/03)
The stereoselective Horner-Wadsworth-Emm...
350-90-3 Process route
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350-99-2
ethyl (E/Z)-2-fluoro-3-phenylprop-2-enoate
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-
350-90-3
(Z/E)-2-fluoro-3-phenylprop-2-enoic acid
| Conditions | Yield |
|---|---|
|
With
sodium hydroxide;
|
96.5%
|
|
(hydrolysis);
|
-
-
30094-32-7
(diethoxy phosphoryl) fluoroacetic acid
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-
100-52-7
benzaldehyde
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-
350-90-3
(Z/E)-2-fluoro-3-phenylprop-2-enoic acid
| Conditions | Yield |
|---|---|
|
With
n-butyllithium;
In
tetrahydrofuran;
at 0 ℃;
for 12h;
|
350-90-3 Upstream products
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370-07-0
2-fluoro-3-phenyl acrylic acid methyl ester
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350-99-2
ethyl (E/Z)-2-fluoro-3-phenylprop-2-enoate
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598-73-2
1-bromo-1,2,2-trifluoroethene
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100-52-7
benzaldehyde
350-90-3 Downstream products
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321-33-5
2,3-dibromo-2-fluoro-3-phenylpropanoic acid
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370-07-0
methyl (Z)-2-fluoro-3-phenylpropenoate
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88410-05-3
(Z)-β-bromo-β-fluorostyrene
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88410-14-4
(E)-1-bromo-1-fluoro-2-phenylethylene